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I had a beer that was men to be an Armageddon clone, lots of hops in the kettle and dry hop, A friend bottled his 23 L and I kegged my 9L back about 1 dec 2013 , I thought it was TOO bitter at the time , left it in keg at back of fridge at 2C since, poured a pint today and it has balance like its lost its harsh bitterness and tastes great going to do a side by side test tomorrow night, have you ever seen this in a beer, It was in carboy for 5 weeks before kegging but it really matured while being kept in a keg at 2C at say 8 psi? 2nd question how long do commercial breweries keep a beer on cold condition before release?
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Is bitterness lost by a chemical reaction?
I honestly couldn't tell you, I don't know whether isomerised alpha acids chemically change to reduce their potency. The non-isomerised hop compounds – aromatics and flavours – definitely drop away over time which could give the perception of less bitterness.
Hopefully one of the 'proper' brewers/chemists can chime in, I'm curious now too!
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